Poly[(μ3-4-aminobenzenesulfonato-κ3 N:O:O)(triphenylphosphine-κP)silver(I)]
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چکیده
In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.
منابع مشابه
Poly[(μ3-4-carboxypyridine-3-carboxylato-κ3 N:O 3:O 4)(triphenylphosphine-κP)silver(I)]
In the title 1:1 silver(I) 4-carb-oxy-pyridine-3-carboxyl-ate adduct with triphenyl-phosphine, [Ag(C(7)H(4)NO(4))(C(18)H(15)P)](n), the carboxyl-ate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag atom exists in a distorted tetra-hedral geometry. The H atom of the carboxyl-ate is midway between ...
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In the crystal structure of {[Ag(C(6)H(4)NO(2))(C(18)H(15)P)]·C(2)H(6)O}(n), the 4-pyridylcarboxyl-ate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitro-gen atom of the aromatic ring, giving a distorted tetra-hedral coordination at the metal atom. The μ(3)-bridging mode ...
متن کاملPoly[(μ3-quinoline-6-carboxylato-κ3 N:O:O′)silver(I)]
In the title coordination polymer, [Ag(C(10)H(6)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from three 6-quinoline-carboxyl-ate anions in a distorted T-shaped AgNO(2) geometry, in which the O-Ag-O angle is 160.44 (9)°. The 6-quinoline-carboxyl-ate anion bridges three Ag(+) cations, forming a nearly planar polymeric sheet parallel to (101). The distance between Ag(+...
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In the title compound, [Ag(2)(C(10)H(6)NO(2))(2)](n), the Ag(I) atom is coordinated by one N atom and two O atoms from three quinoline-3-carboxyl-ate ligands in a T-shaped fashion, with an additional Ag⋯Ag distance of 2.9468 (6) Å. The ligands connect the Ag(I) atoms into a double-chain structure along [010]. Weak Ag⋯O inter-actions [Ag⋯O = 2.802 (3) and 2.877 (4) Å] link the double-chains into...
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The phosphine-coordinated Ag(I) atom in the title compound, [Ag(C(21)H(17)BN(6))(C(18)H(15)P)], is also N,N',N''-chelated by the tris-(indazol-yl)borate anion. The resultant N(3)P coordination geometry is tetra-hedral.
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